Characterization of nanoparticle electrocatalysts using X-ray absorption spectroscopy
نویسندگان
چکیده
منابع مشابه
Chemical characterization and X-ray absorption spectroscopy
A rapid progress in the theoretical developments based on modulations of absorption cross section due to single and multiple scattering of an electron emitted from an inner shell by X-rays impinging on the target atom to understand the EXAFS and XANES in recent years and harnessing of the highly powerful synchrotron radiation source for the X-rays have bestowed immense capability on X-ray absor...
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Strong characteristic Kα X-ray lines are accompanied by weak lines due to the radiative Auger effect (RAE) [1, 2]. The characteristic Kα fluorescent X-rays (K-L2,3 lines) are emitted by the 2p→1s electric dipole transition after one of the 1s electron photoionization, Though the probability is less than 0.01, one of the 2p electrons is excited into an unoccupied discrete or continuum level simu...
متن کاملX-ray Absorption Spectroscopy
X-ray absorptioń spectroscopy, today widely used as a tool for structural investigations, is described. Theoretically it is shown that above an absorption edge the absorption coefficient is well approximated by a sum of terms, each one describing a particular path followed by the photoelectron outgoing from the atom. Such geometrical feature allows to use X-ray absorption spectroscopy for struc...
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1.59.1 PHYSICS OF X-RAY ABSORPTION 1 1.59.1.1 X-ray Absorption Edges 2 1.59.1.2 X-ray Fluorescence 3 1.59.1.3 Measurement of X-ray Absorption Spectra 3 1.59.2 EXTENDED X-RAY ABSORPTION FINE STRUCTURE 6 1.59.2.1 Theoretical Description of EXAFS Spectra 6 1.59.2.1.1 Single scattering 6 1.59.2.1.2 Multiple scattering 8 1.59.2.1.3 Other corrections to the EXAFS equation 9 1.59.2.2 Programs for Calc...
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The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We have investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH₃(CH₂)15N⁺(CH₃)₃Br-) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically ...
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ژورنال
عنوان ژورنال: Zastita materijala
سال: 2015
ISSN: 0351-9465
DOI: 10.5937/zasmat1504463m